Fanelli, Fiorenza and Fracassi, Francesco and d'Agostino, Riccardo (2008) Fluorination of Polymers by Means of He/CF4‐Fed Atmospheric Pressure Glow Dielectric Barrier Discharges. Plasma Processes and Polymers, 5 (5). pp. 424-432. ISSN 1612-8850
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Abstract
He/CF4-fed GDBDs were used to fluorinate PP and PET. The effect of various process parameters on the polymers surface composition and morphology, as well as on their wettability was investigated inside the GDBD existence domain. An extensive surface fluorination of treated polymers due to the grafting of F atoms and CFx radicals was observed. The increase of CF4 concentration in the feed, of treatment duration, and of excitation frequency resulted in an increase of the fluorination degree corresponding to F/C ratios as high as 1.18 and 1.22 for PP and PET, respectively. The emission spectra of GDBDs fed by helium in mixture with CF4, CHF3, C2F6 and C3F8 were compared.
| Item Type: | Article |
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| Uncontrolled Keywords: | atmospheric pressure glow discharges (APGD); dielectric barrier discharges (DBD); fluorination; polymer treatment; optical emission spectroscopy (OES) |
| Subjects: | 500 Scienze naturali e Matematica > 500.2 Scienze fisiche 500 Scienze naturali e Matematica > 540 Chimica e scienze connesse |
| Depositing User: | Fiorenza Fanelli |
| Date Deposited: | 26 Jan 2024 14:22 |
| Last Modified: | 26 Jan 2024 14:22 |
| URI: | http://eprints.bice.rm.cnr.it/id/eprint/22646 |
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