Non-equilibrium evolution of stratospheric particles under multi-components diffusive condensation/evaporation regime

Rizi, V. and Visconti, G. (2001) Non-equilibrium evolution of stratospheric particles under multi-components diffusive condensation/evaporation regime. Il nuovo cimento C, 24 C (3). pp. 341-352. ISSN 1826-9885

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Abstract

A box model is used to study the evolution of stratospheric HNO3/H2SO4/H2O solution particles along temperature variations, which force the droplet ensemble far from the thermodynamic equilibrium. In the case of rapid temperature fluctuations, i.e. orographically forced lee waves, the model shows that the micron-sized droplets meet the conditions to become precursors of solid particles, mainly constituted of nitric acid hydrates. This paper examines how the particle size distributions and compositions are influenced by the presence of rapid temperature fluctuations, comparing model calculations along prescribed thermal histories. There results a remarkable dependence of the particle physical status (solid and/or liquid) on the presence of wave-like perturbations in the former thermal history of the air mass.

Item Type: Article
Uncontrolled Keywords: Particles and aerosols ; Chemical composition and chemical interactions
Subjects: 300 Scienze sociali > 360 Problemi e servizi sociali; associazioni > 363 Altri problemi e servizi sociali > 363.7 Problemi ambientali (classificare qui la tutela ambientale; l’effetto dei rifiuti, dell’inquinamento, delle iniziative per controllarli) > 363.73 Inquinamento > 363.739 Inquinamento di specifici ambienti > 363.7392 Inquinamento atmosferico
Depositing User: Marina Spanti
Date Deposited: 10 Mar 2020 18:32
Last Modified: 10 Mar 2020 18:32
URI: http://eprints.bice.rm.cnr.it/id/eprint/14251

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