Processing, compatibilization and properties of ternary composites of Mater-Bi with polyolefins and hemp fibres

Haque, Md. Minhaz-Ul and Alvarez, Vera and Paci, Massimo and Pracella, Mariano (2011) Processing, compatibilization and properties of ternary composites of Mater-Bi with polyolefins and hemp fibres. Composites. Part A: Applied science and manufacturing, 42A (12). pp. 2060-2069. ISSN 1359-835X

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Abstract

Ternary composites of a biodegradable thermoplastic matrix, Mater-Bi (MB), with various polyolefins (PP, HDPE and PS) and hemp fibres (H) were obtained by melt mixing and characterized by SEM, OM, DSC, TGA and tensile tests. The properties of composites were compared with those of MB/polyolefin and MB/H blends. Maleic anhydride functionalized polyolefins were employed as compatibilizers. Crystallization behaviour and morphology of the composites were found to be affected by the composition, phase dispersion and compatibilizer. Thermogravimetric analysis indicated that the thermal stability of the polyolefin phase and fibres was influenced by the composition and phase structure. A significant improvement of tensile modulus and strength was recorded for composites of MB with PE and PS as compared to MB/H composites. The results indicate that incorporation of polyolefins in the biodegradable matrix, compared to binary matrix/fibre system, may have significant advantages in terms of properties, processability and cost.

Item Type: Article
Additional Information: Questo articolo è il risultato delle ricerche effettuate nell'ambito dell'accordo di coopearzione tra l'Istituto per i Materiali Compositi e Biomedici (IMCB) del CNR e l'Instituto de Investigaciones en Ciencia y Tecnologia de Materiales (INTEMA) del Consejo Nacional de Investigaciones Científicas y Técnicas (CONICET)(responsabili scientifici Mariano Pracella CNR-IMCB e Vera Alvarez CONICET - INTEMA)
Uncontrolled Keywords: Polymer-matrix composites (PMCs), Fibres, Mechanical properties, Thermal properties
Subjects: 600 Tecnologia - Scienze applicate > 660 Ingegneria chimica
600 Tecnologia - Scienze applicate > 660 Ingegneria chimica > 668 Tecnologia di altri prodotti organici > 668.9 Polimeri e polimerizzazione
Depositing User: biblioteca 7
Date Deposited: 06 Nov 2011 09:39
Last Modified: 06 Nov 2011 09:43
URI: http://eprints.bice.rm.cnr.it/id/eprint/3718

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